Alcohols are identified as having an -OH (hydroxyl) functional group attached to the parent chain. This (relatively) strong intermolecular force increases alcohol melting and boiling points. Because of the -OH atoms, alcohols are polar. However as the carbon chain (non-polar) increases in length, the overall polarity will become less polar.
Alcohols can be made from haloalkanes and from oxidation of alkenes. Alcohols
can undergo substitution, elimination, and oxidation reactions. For substitution
reactions PCl3 or SOCl2 are sources of Cl, which replaces
the -OH group. Elimination of alcohols to form alkenes is also a 'dehydration'
reaction (concentrated H2SO4 reagent). ONLY primary
alcohols oxidise to form carboxylic acids. Oxidants such as potassium
permanganate (KMnO4) and potassium dichromate
(K2Cr2O7) are reagents for this reaction.
Potassium permanganate is purple and turns colourless when it reacts. Potassium
dichromate is orange and turns green.
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